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Silane, triphenyl(3-phenyloxiranyl)-, cis- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

90159-01-6

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90159-01-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 90159-01-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,1,5 and 9 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 90159-01:
(7*9)+(6*0)+(5*1)+(4*5)+(3*9)+(2*0)+(1*1)=116
116 % 10 = 6
So 90159-01-6 is a valid CAS Registry Number.

90159-01-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name (Z)-1-Phenyl-2-triphenylsilyl-oxirane

1.2 Other means of identification

Product number -
Other names Triphenyl-((2S,3R)-3-phenyl-oxiranyl)-silane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:90159-01-6 SDS

90159-01-6Downstream Products

90159-01-6Relevant academic research and scientific papers

STEREOSPEZIFISCHE CARBONYL(Z)OXIRANIERUNG VON BENZALDEHYD MIT IODO-TRIPHENYLSILYL- UND IODO-TRIPHENYLGERMYL-METHYLLITHIUM (1)

Kauffmann, Thomas,Koenig, Rolf,Wensing, Michael

, p. 637 - 640 (2007/10/02)

The reagents Ph3M-CH(I)Li (M=Si, Ge) react with benzaldehyde via anionic benzaldehyde adducts stereospecifically to give (Z)-1-phenyl-2-triphenylsilyl- (7a) or (Z)-1-phenyl-2-triphenylgermyl-oxirane (7b), respectively.By protolysis of the anionic benzaldehyde adducts at -65 deg C corresponding iodohydrins (5a,5b) have been obtained.

STEREOSPEZIFISCHE CARBONYLOLEFINIERUNG WAHLWEISE ZU EINEM (Z)- ODER (E)-OLEFIN MIT DEN REAGENZIEN IODO-TRIPHENYLSILYL- UND IODO-TRIPHENYLGERMYL-METHYLLITHIUM OHNE TRENNUNG DIASTEREOMERER ZWISCHENPRODUKTE (1)

Kauffmann, Thomas,Koenig, Rolf,Kriegesmann, Reinhard,Wensing, Michael

, p. 641 - 644 (2007/10/02)

The recently found (1) stereospecific transformation of benzaldehyde by the reagents Ph3M-CH(I)Li (M= Si, Ge) to Ph3M-substituted oxiranes renders possible a method for olefination of benzaldehyde to give Z- or E-olefins, alternatively.This is demonstrated with two examples. - The synthesis of Ph3Sn-CH(I)Li is described.

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