90159-05-0

Basic information

• Product Name: 2-Iodo-1-phenyl-2-triphenylsilanyl-ethanol
• Synonyms: 2-Iodo-1-phenyl-2-triphenylsilanyl-ethanol
• CAS NO: 90159-05-0
• Molecular Weight: 506.458
• Mol File: 90159-05-0.mol

Chemical Properties

• CAS DataBase Reference: 2-Iodo-1-phenyl-2-triphenylsilanyl-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Iodo-1-phenyl-2-triphenylsilanyl-ethanol(90159-05-0)
• EPA Substance Registry System: 2-Iodo-1-phenyl-2-triphenylsilanyl-ethanol(90159-05-0)

Safety Data

• Hazardous Substances Data: 90159-05-0(Hazardous Substances Data)

Upstream product

• 18670-59-2 (Diiodmethyl)triphenylsilan 
• 100-52-7 benzaldehyde 
• 76-86-8 Triphenylsilyl chloride 

Downstream Products

• 90159-01-6 (Z)-1-Phenyl-2-triphenylsilyl-oxirane 

Relevant articles and documents

STEREOSPEZIFISCHE CARBONYL(Z)OXIRANIERUNG VON BENZALDEHYD MIT IODO-TRIPHENYLSILYL- UND IODO-TRIPHENYLGERMYL-METHYLLITHIUM (1)

The reagents Ph3M-CH(I)Li (M=Si, Ge) react with benzaldehyde via anionic benzaldehyde adducts stereospecifically to give (Z)-1-phenyl-2-triphenylsilyl- (7a) or (Z)-1-phenyl-2-triphenylgermyl-oxirane (7b), respectively.By protolysis of the anionic benzaldehyde adducts at -65 deg C corresponding iodohydrins (5a,5b) have been obtained.