902137-42-2Relevant academic research and scientific papers
An improved synthesis of (-)-martinellic acid via radical addition-cyclization-elimination reaction of chiral oxime ether
Miyata, Okiko,Shirai, Atsushi,Yoshino, Shintaro,Takeda, Yoshifumi,Sugiura, Makiko,Naito, Takeaki
, p. 893 - 896 (2007/10/03)
A concise formal synthesis of (-)-martinellic acid has been accomplished by preparing optically active dipyrroloquinoline as a key synthetic intermediate, which was prepared via the radical addition-cyclization-elimination of oxime ether carrying an unsaturated ester followed by two chemoselective reductions of the carbonyl groups. Georg Thieme Verlag Stuttgart.
