90243-47-3

Upstream product

• 90180-88-4 (R)-(-)-3-mercaptohexan-1-ol 
• 75-07-0 acetaldehyde 
• 90180-90-8 (+)-(S)-3-mercaptohexan-1-ol 
• 136954-20-6 3-mercaptohex-1-yl acetate 
• 92610-81-6 (R,R)-3-Propylthiiran-2-methanol 
• 92693-35-1 (2S,3S)-2,3-epithio-1-hexanol 
• 92418-71-8 (2R,3R)-2,3-epoxy-1-hexanol 
• 89321-71-1 (2S,3S)-3-propyl-2-oxiranemethanol 

Relevant academic research and scientific papers

1,3-Oxathianes, Chiral Fruit Flavour Compounds

From optically pure 3-mercaptohexan-1-ols as key intermediates some chiral 1,3-oxathianes were synthesized and their structures elucidated by 1H and 13C NMR spectra.Sensory qualities of the optically pure isomers are given.

Enantioselective Synthesis of (+)- and (-)-cis-2-methyl-4-propyl-1,3-oxathiane and their Olfactive Properties

The enantioselective synthesis of (+)- and (-)-cis-2-methyl-4-propyl-1,3-oxathiane 8 and 9 from (E)-2-hexen-1-ol (1) as common starting material is described.The two enantiomeric forms exhibit different organoleptic properties.

CHIRALE, SCHWEFELHALTIGE AROMASTOFFE DER GELBEN PASSIONSFRUCHT (PASSIFLORA EDULIS F. FLAVICARPA). DARSTELLUNG DER ENANTIOMEREN UND ABSOLUTE KONFIGURATION

3-Methylthio-hexane-1-ol and 2-methyl-4-propyl-1,3-oxathiane, chiral S-containing aroma substances of the yellow passion fruit are resolved to enantiomers and absolute configurations are elucidated.