90348-22-4Relevant academic research and scientific papers
Synthesis of a polythieno[3,4-b]thiophene derivative with a low-lying HOMO level and its application in polymer solar cells
Huo, Lijun,Guo, Xia,Li, Yongfang,Hou, Jianhui
, p. 8850 - 8852 (2011)
A planar benzodithiophene with lower HOMO was copolymerized with the thieno[3,4-b]thiophene unit to obtain a new low band gap polymer of PBDPTT-C, which exhibited a higher open-circuit voltage (Voc) of 0.8 V and a promising efficiency of 5.2%.
Synthesis of alkylated benzo[2,1-b:3,4-6′]dithiophenes by annulative coupling and their direct arylation under palladium catalysis
Watanabe, Hiroyuki,Kumagai, Jun,Tsurugi, Hayato,Satoh, Tetsuya,Miura, Masahiro
, p. 1336 - 1337 (2007)
The annulative coupling of 3,3′-diiodo-2,2′-bithiophene with internal alkynes efficiently proceeds in the presence of a palladium catalyst to afford the corresponding benzo[2,1-b:3,4-b′]dithiophene derivatives. The dithiophenes also undergo palladium-cata
Dithienopyrrole Derivatives with Nitronyl Nitroxide Radicals and Their Oxidation to Cationic High-Spin Molecules
Baumgarten, Martin,Kolanji, Kubandiran
supporting information, (2020/03/13)
Three 1 N-phenyl nitronyl nitroxide (NN) 4-substituted dithieno[3,2-b:2′,3′-d]pyrrole (DTP) derivatives with R1=4-phenyl-, 4H-, and 4-methylthiothiophenyl- (R12DTP-Ph-NN, R1=H, Ph and MeSTh) were designed, synthesized and
Substantial photovoltaic response and morphology tuning in benzo[1,2-b:6,5-b′]dithiophene (bBDT) molecular donors
Harschneck, Tobias,Zhou, Nanjia,Manley, Eric F.,Lou, Sylvia J.,Yu, Xinge,Butler, Melanie R.,Timalsina, Amod,Turrisi, Riccardo,Ratner, Mark A.,Chen, Lin X.,Chang, Robert P. H.,Facchetti, Antonio,Marks, Tobin J.
supporting information, p. 4099 - 4101 (2014/04/03)
The influence of solubilizing substituents on the photovoltaic performance and thin-film blend morphology of new benzo[1,2-b:6,5-b′]dithiophene (bBDT) based small molecule donor semiconductors is investigated. Solar cells based on bBDT(TDPP)2-PC71BM with two different types of side chains exhibit high power conversion efficiencies, up to 5.53%. This journal is the Partner Organisations 2014.
Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent
Dohi, Toshifumi,Ito, Motoki,Yamaoka, Nobutaka,Morimoto, Koji,Fujioka, Hiromichi,Kita, Yasuyuki
experimental part, p. 10797 - 10815 (2010/03/01)
In 1994, we first determined the single-electron-transfer (SET) oxidation ability of phenyliodine(III) bis(trifluoroacetate) (PIFA) toward phenyl ethers, affording the corresponding aromatic cation radicals. Since then, hypervalent iodine(III) has been utilized as a selective and efficient SET oxidizing agent that enables a variety of direct C-H functionalizations of aromatic rings in electron-rich arenes under mild conditions. We have now extended the original method to work in a series of heteroaromatic compounds such as thiophenes, pyrroles, and indoles. The investigations and results obtained since the start of this century are summarized in this article.
PROCESS FOR PRODUCTION OF FUSED RING COMPOUND
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Page/Page column 5, (2009/07/03)
It is an object of the present invention to provide a method for manufacturing a fused ring compound, with which a fused ring compound that has excellent charge transport property and that has excellent solubility in solvents can be obtained efficiently. The method of the present invention for manufacturing a fused ring compound involves reacting a compound expressed by the following General Formula (1a) and a compound expressed by the following General Formula (1b) in the presence of an amine and a metal complex catalyst: (where Ar11 and Ar12 are each independently an atom group constituting an aromatic ring or a heterocyclic ring; X11 and X12 are each independently a hydrogen atom or a halogen atom, and at least one is a halogen atom; and R11 and R12 are each independently a hydrogen atom, an all group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an aryl group, a heterocyclic group, or a cyano group, provided that at least one of R11 and R12 is not a hydrogen atom).
FUSED RING COMPOUND AND METHOD FOR PRODUCING SAME, POLYMER, ORGANIC THIN FILM CONTAINING THOSE, AND ORGANIC THIN FILM DEVICE AND ORGANIC THIN FILM TRANSISTOR COMPRISING SUCH ORGANIC THIN FILM
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Page/Page column 17, (2009/01/24)
It is an object of the present invention to provide a fused ring compound which can exhibit sufficient charge transport properties and which has excellent solubility in a solvent. The fused ring compound according to the present invention is represented b
