90553-72-3Relevant academic research and scientific papers
Chloroaluminate(III) ionic liquid mediated synthesis of transition metal-cyclophane; Complexes: Their role as solvent and Lewis acid catalyst1
Crofts, David,Dyson, Paul J.,Sanderson, Katharine M.,Srinivasan, Narmatha,Welton, Thomas
, p. 292 - 298 (1999)
The preparation of transition metal-cyclophane complexes using the ionic liquid system [bmim]Cl-AlCl3 ([bmim]+=1-butyl-3-methylimidazolium cation) as both the solvent and Lewis acid catalyst is described. Both known and novel complex
Manganese-Mediated Reductions of Arenes to Cyclohexa-1,3-dienes via Mn-H-C Bridged Cyclohexenylmanganese Tricarbonyl Complexes
Brookhart, M.,Lukacs, Alexander
, p. 4161 - 4166 (1984)
Conversions of cationic manganese tricarbonyl comlexes of toluene, 1a, o-xylene, 1b, biphenyl, 1c, and anisole, 1d, to free cyclohexa-1,3-dienes are reported.The reaction sequence involves double hydride reduction of 1a-d and protonation to give the M-H-C
