90606-24-9Relevant academic research and scientific papers
AZOMETHINE YLIDE PRECURSORS: A SIMPLE ROUTE TO N-(TRIMETHYLSILYLMETHYL) IMINES
Letellier, M.,McPhee, D. J.,Griller, D.
, p. 1975 - 1978 (2007/10/02)
A simple synthesis of N-(trimethylsilylmethyl)amine is reported.This compounds was used to prepare N-(trimethylsilylmethyl)amines, useful sources of "nonstabilized" azomethine ylides.
One-Pot Synthesis of N-((Trimethylsilyl)methyl)imines and (Trimethylsilyl)methyl-Substituted Heterocumulenes from (Trimethylsilyl)methyl Azide
Tsuge, Otohiko,Kanemasa, Shuji,Matsuda, Koyo
, p. 2688 - 2691 (2007/10/02)
The reactions of ((trimethylsilyl)methyl)iminotriphenylphosphorane, prepared in situ from (trimethylsilyl)methyl azide and triphenylphosphine, with carbonyl compounds and with heterocumulenes such as carbon dioxide, carbon disulfide, isocyanates, isothiocyanates, and a ketene provide convenient one-pot syntheses of the corresponding N-((trimethylsilyl)methyl)imines and (trimethylsilyl)methyl-substituted heterocumulenes, which are versatile reagents for the synthesis of heterocyclic compounds.
