906482-51-7

Basic information

• Product Name: 2-(4-Trifluoromethyl-phenyl)-2-trimethylsilanyloxy-propionitrile
• Synonyms: 2-(4-Trifluoromethyl-phenyl)-2-trimethylsilanyloxy-propionitrile
• CAS NO: 906482-51-7
• Molecular Weight: 287.357
• Mol File: 906482-51-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(4-Trifluoromethyl-phenyl)-2-trimethylsilanyloxy-propionitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-Trifluoromethyl-phenyl)-2-trimethylsilanyloxy-propionitrile(906482-51-7)
• EPA Substance Registry System: 2-(4-Trifluoromethyl-phenyl)-2-trimethylsilanyloxy-propionitrile(906482-51-7)

Safety Data

• Hazardous Substances Data: 906482-51-7(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 709-63-7 1-(4-trifluoromethylphenyl)ethanone 
• 455-19-6 4-Trifluoromethylbenzaldehyde 

Downstream Products

• 82026-76-4 α-hydroxy-α-methyl-4-(trifluoromethyl)benzeneacetonitrile 
• 82026-82-2 Methanesulfonic acid cyano-methyl-(4-trifluoromethyl-phenyl)-methyl ester 
• 81561-66-2 2-hydroxy-2-(4-trifluoromethylphenyl)ethanamine 
• 1383925-61-8 (+/-)-2-(pyrid-2-yl)-5-[4-(trifluoromethyl)phenyl]-1,3-oxazoline 

Relevant articles and documents

[Mes-B-TMP]+borinium cation initiated cyanosilylation and catalysed hydrosilylation of ketones and aldehydes

Two aryl amino borinium cations derived from Cl(Mes)B-NR2(NR2= TMP, HMDS) faced divergent outcomes. As the HMDS-substituted one underwent methyl migration from silicon to boron transforming the putative borinium ion to a silylium ion, [Mes-B-TMP]+can initiate cyanosilylation and catalyse hydrosilylation of ketones and aldehydes.

Influence of an α-Cyano Function on Charge Delocalization in the Benzyl Cation. Relationship between Inductive Destabilization and Conjugative Stabilization by the Cyano Group

The solvolytic behavior of a series of substituted acetophenone cyanohydrin methanesulfonates has been studied in 2,2,2-trifluoroethanol.A ρ value of -6.70 was observed when the rate data was evaluated vs.Brown's ?+ values.