906543-39-3Relevant academic research and scientific papers
"Clickphine": A novel and highly versatile P,N ligand class via click chemistry
Detz, Remko J.,Heras, Silvia Arevalo,De Gelder,Van Leeuwen, Piet W. N. M.,Hiemstra, Henk,Reek, Joost N. H.,Van Maarseveen, Jan H.
, p. 3227 - 3230 (2006)
A novel P,N-type ligand family (ClickPhine) is disclosed that is easily accessible using the Cu(I)-catalyzed azide-alkyne "click" cycloaddition. A diverse set of ligands was made in just three steps from readily available starting materials to give several homogeneous and a heterogeneous catalyst. Preliminary experiments show the efficacy of these ligands in the Pd-catalyzed allylic alkylation reaction.
