90762-83-7

Upstream product

• 389065-68-3 (2R,4R,6S)-4-Benzyloxy-6-methoxy-2-methyl-dihydro-pyran-3-one 
• 874788-94-0 Toluene-4-sulfonic acid (2R,3S,4R,6S)-4-benzyloxy-3-hydroxy-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 18546-25-3 6-O-p-tolylsulfonyl-3,4-di-O-acetyl-D-glucal 
• 363134-99-0 diacetyl-d-glucal-6-bromohydrin 
• 86651-49-2 methyl 3,4-di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 76739-66-7 3,4-di-O-acetyl-D-rhamnal 
• 2873-29-2 D-glucal triacetate 
• 65556-00-5 methyl 4,6-di-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 119943-96-3 Methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-arabino-hexopyranoside 
• 6752-48-3 methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 67-56-1 methanol 
• 106062-15-1 lyxo-4-O-Benzylhept-1-ene-4,5,6-triol 
• 106062-14-0 (4S,5R)-4-((R)-1-Benzyloxy-but-3-enyl)-2,2,5-trimethyl-[1,3]dioxolane 

Downstream Products

• 939050-75-6 methyl 3-O-benzyl-4-O-(3-O-benzyl-4-O-benzylsulfonyl-2,6-dideoxy-β-D-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 20585-98-2 methyl α-curacinoside 
• 116217-59-5 methyl 4-O-(4-benzyloxy-3,5-dichloro-2-methoxy-6-methylbenzoyl)-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 90762-90-6 Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-2,6-diiodo-α-D-mannopyranosyl)-3-O-benzyl-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 131013-38-2 tert-Butyldimethylsilyl 4-O-Acetyl-3-(3-O-benzyl-2,6-dideoxy-4-O-methyl-α-D-lyxo-pyranosyl)-2,6-dideoxy-α-D-lyxo-pyranoside 
• 131013-40-6 tert-Butyldimethylsilyl 4-O-Acetyl-3-(3-O-benzyl-2,6-dideoxy-4-O-methyl-α-D-lyxo-pyranosyl)-2,6-dideoxy-β-D-lyxo-pyranoside 
• 131013-41-7 tert-Butyldimethylsilyl 4-O-Acetyl-3-(3-O-benzyl-2,6-dideoxy-4-O-methyl-β-D-lyxo-pyranosyl)-2,6-dideoxy-β-D-lyxo-pyranoside 
• 131041-37-7 4-O-Acetyl-3-(3-O-benzyl-2,6-dideoxy-4-O-methyl-α-D-lyxo-pyranosyl)-2,6-dideoxy-α-D-lyxo-pyranose 
• 131013-42-8 4-O-Acetyl-3-(3-O-benzyl-2,6-dideoxy-4-O-methyl-α-D-lyxo-pyranosyl)-2,6-dideoxy-β-D-lyxo-pyranose 
• 106023-22-7 (2R,3S,4R)-4-Benzyloxy-3-methoxy-2-methyl-6-phenylsulfanyl-tetrahydro-pyran 
• 106023-24-9 Acetic acid (2R,3S,4R,6S)-4-((2R,4R,5S,6R)-4-benzyloxy-5-methoxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 3868-01-7 methyl 2,6-dideoxy-3-O-benzyl-4-O-methyl-α-D-lyxo-hexopyranoside 
• 4833-12-9 methyl 4-O-acetyl-3-O-benzyl-2,6-dideoxy-α-D-lyxo-hexopyranoside 
• 121330-36-7 4-O-benzoyl-3-O-benzyl-2,6-dideoxy-α-D-arabino-hexopyranose 

Relevant academic research and scientific papers

Direct and stereoselective synthesis of β-linked 2,6- deoxyoligosaccharides

(Chemical Equation Presented) Short and sweet: Glycosidation of 2-deoxyglycosyl imidates with I2 as shown in the scheme (Bn = benzyl, Bz = benzoyl, MS = molecular sieves) proceeds smoothly to provide the corresponding β-linked 2-deoxyglycosides

Novel and convenient method for the syntheses of 2,6-dideoxypyranoses, 3,6-dideoxypyranoses, and azido (amino) analogs of 3,6-dideoxypyranoses

A novel method of regioselective deoxygenation of methyl 4,6-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside, and its application for the syntheses of 2,6-dideoxypyranoses, 3,6-dideoxypyranoses, and azido (amino) analogs of 3,6-dideoxypyranoses were reported.

Studies of the stereoselective reduction of ketosugar (hexosulose)

The results from the studies of the stereoselective reduction of ketosugar (hexosulose) were reported. Combining our results and those reported in the literature, we summarize the factors in controlling the stereoselective reduction of ketosugars. These findings are valuable in the synthesis of various carbohydrate derivatives.

A Highly Stereoselective Synthesis of the AB Disaccharide Unit of Olivomycin A

A highly stereoselective synthesis of the AB disaccharide (4c) of olivomycin A is described.The synthesis features the double asymmetric allylboration of α,β-dialkoxy aldehyde 8 using tartrate allylboronate (S,S)-9, which provides triol derivative 10 with