908865-85-0

Upstream product

• 908866-05-7 (2S,3S,4aS,9aR)-2-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocyclohepten-6-one 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 127793-62-8 4-((tert-butyldiphenylsilyl)oxy)butanal 
• 908866-38-6 (3S,4S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-heptanal 
• 908865-92-9 (2S,3S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2-methyl-hexan-1-ol 
• 924656-30-4 (2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-2,5-dimethyl-2-vinyl-tetrahydro-pyran-3-ol 
• 908865-90-7 (2S,3S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-hexane-1,3-diol 
• 908865-94-1 (3S,4S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-heptanenitrile 
• 908866-01-3 (2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-2,5-dimethyl-3-triethylsilanyloxy-2-vinyl-tetrahydro-pyran 
• 908865-95-2 (E)-(5S,6S)-9-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-2,5-dimethyl-non-2-en-1-ol 
• 908865-99-6 tert-Butyl-[(4S,5S)-4-(4-methoxy-benzyloxy)-5-methyl-6-((2S,3S)-3-methyl-3-vinyl-oxiranyl)-hexyloxy]-diphenyl-silane 
• 908865-97-4 {(2S,3S)-3-[(2S,3S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2-methyl-hexyl]-2-methyl-oxiranyl}-methanol 
• 908866-42-2 4-{(2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-2,5-dimethyl-tetrahydro-pyran-2-yl}-butyric acid 
• 908866-37-5 (R)-4-Benzyl-3-[(2R,3S)-6-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-2-methyl-hexanoyl]-oxazolidin-2-one 

Downstream Products

• 924656-70-2 C₅₈H₉₈O₉Si₃ 
• 908866-46-6 C₅₈H₉₈O₉Si₃ 
• 924656-51-9 C₆₀H₉₂O₉SSi₂ 
• 908866-26-2 C₆₀H₉₂O₉SSi₂ 
• 924656-68-8 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol 
• 908866-21-7 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol 
• 908866-22-8 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-hexahydro-1,5-dioxa-benzocyclohepten-7-one 
• 924656-53-1 C₆₅H₁₀₄O₉Si₃ 
• 908866-28-4 C₆₅H₁₀₄O₉Si₃ 
• 924656-48-4 C₆₆H₉₆O₁₁Si₂ 
• 908866-23-9 C₆₆H₉₆O₁₁Si₂ 
• 924656-54-2 C₆₄H₁₁₂O₉Si₄ 
• 908866-29-5 C₆₄H₁₁₂O₉Si₄ 
• 924656-52-0 C₆₆H₁₀₆O₉SSi₃ 

Relevant academic research and scientific papers

Total synthesis of the proposed structure of brevenal

Total synthesis of the proposed structure of brevenal, a natural marine polycyclic ether product, has been accomplished. The synthesis features (i) convergent synthesis of the pentacyclic polyether skeleton using our developed Suzuki-Miyaura coupling stra

Total synthesis, structure revision, and absolute configuration of (-)-brevenal

Total synthesis of structure 1 originally proposed for brevenal, a nontoxic polycyclic ether natural product isolated from the Florida red tide dinoflagellate, Karenia brevis, was accomplished. The key features of the synthesis involved (i) convergent ass