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91-30-5

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91-30-5 Usage

General Description

4-Aminodiphenyamine-2-sulfonic acid is an aromatic compound that consists of a central benzene ring with two amine groups and one sulfonic acid group attached to it. It is often used as a building block for the synthesis of a variety of dyes, pigments, and other organic compounds. This chemical is water-soluble and has the potential to be toxic to aquatic organisms. It is important to handle and dispose of 4-Aminodiphenyamine-2-sulfonic acid with caution to minimize environmental impact.

Check Digit Verification of cas no

The CAS Registry Mumber 91-30-5 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 9 and 1 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 91-30:
(4*9)+(3*1)+(2*3)+(1*0)=45
45 % 10 = 5
So 91-30-5 is a valid CAS Registry Number.
InChI:InChI=1/C12H12N2O3S/c13-9-6-7-11(12(8-9)18(15,16)17)14-10-4-2-1-3-5-10/h1-8,14H,13H2,(H,15,16,17)

91-30-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-amino-2-anilinobenzenesulfonic acid

1.2 Other means of identification

Product number -
Other names Nerolsaeure

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:91-30-5 SDS

91-30-5Synthetic route

p-nitrosodiphenylamine
156-10-5

p-nitrosodiphenylamine

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

Conditions
ConditionsYield
With sodium sulfite
With sodium hydroxide; sodium sulfite Ansaeuern der Loesung;
2-anilino-5-nitro-benzenesulfonic acid
88-35-7

2-anilino-5-nitro-benzenesulfonic acid

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

Conditions
ConditionsYield
With hydrogenchloride; iron
With hydrogenchloride; iron
barium salt of/the/ 4-nitro-diphenylamine-sulfonic acid-(2)

barium salt of/the/ 4-nitro-diphenylamine-sulfonic acid-(2)

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

Conditions
ConditionsYield
With barium dihydroxide; iron(II) sulfate
sodium salt of/the/ 4-nitro-diphenylamine-sulfonic acid-(2)

sodium salt of/the/ 4-nitro-diphenylamine-sulfonic acid-(2)

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

Conditions
ConditionsYield
With water; zinc
With water; zinc
aniline
62-53-3

aniline

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: glycerol; calcium carbonate / 180 - 185 °C
2: iron powder; hydrochloric acid
View Scheme
4-hydroxy-1-methyl-2(1H)-quinolone
1677-46-9

4-hydroxy-1-methyl-2(1H)-quinolone

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

(E)-5-((4-hydroxy-1-methyl-2-oxo-1,2-dihydroquinolin-yl)diazenyl)2(phenylamino)benzenesulfonic acid

(E)-5-((4-hydroxy-1-methyl-2-oxo-1,2-dihydroquinolin-yl)diazenyl)2(phenylamino)benzenesulfonic acid

Conditions
ConditionsYield
Stage #1: 4-aminodiphenylamine-2-sulfonic acid With sodium carbonate In water at 0 - 5℃;
Stage #2: With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 0.833333h;
Stage #3: 4-hydroxy-1-methyl-2(1H)-quinolone With sodium hydroxide at 0 - 5℃; for 4h; pH=6 - 7;
74.9%
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

A

C24H18N4O6S2

C24H18N4O6S2

B

C24H20N4O6S2

C24H20N4O6S2

Conditions
ConditionsYield
With recombinant CotA-laccase from Bacillus subtilis In methanol; aq. phosphate buffer at 37℃; for 24h; pH=6; Kinetics; Green chemistry; Enzymatic reaction;A 70%
B 27%
1-amino-4-bromo-2-(hydroxymethyl)anthraquinone
24094-46-0

1-amino-4-bromo-2-(hydroxymethyl)anthraquinone

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

C27H21N3O6S

C27H21N3O6S

Conditions
ConditionsYield
With potassium acetate; copper diacetate at 95℃; for 0.583333h; Ullmann Condensation; Microwave irradiation;57%
1-Amino-4-bromoanthraquinone-2-carboxylic acid
6363-90-2

1-Amino-4-bromoanthraquinone-2-carboxylic acid

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

sodium 1-amino-4-[4-phenylamino-3-carboxyphenylamino]-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate
1052087-99-6

sodium 1-amino-4-[4-phenylamino-3-carboxyphenylamino]-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate

Conditions
ConditionsYield
With copper at 120℃; for 0.0833333h; Ullmann reaction; aq. phosphate buffer; Microwave irradiation;55%
1-amino-4-bromo-9,10-dioxoanthracene-2-sulphonic acid
116-81-4

1-amino-4-bromo-9,10-dioxoanthracene-2-sulphonic acid

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

disodium 1-amino-4-[4-phenylamino-3-sulfophenylamino]-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate

disodium 1-amino-4-[4-phenylamino-3-sulfophenylamino]-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate

Conditions
ConditionsYield
With copper at 120℃; for 0.0833333h; Ullmann reaction; aq. phosphate buffer; Microwave irradiation;46%
1-amino-4-bromo-9,10-dioxo-9,10-dihydroanthracene-2-carbonitrile

1-amino-4-bromo-9,10-dioxo-9,10-dihydroanthracene-2-carbonitrile

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

C27H18N4O5S

C27H18N4O5S

Conditions
ConditionsYield
With potassium acetate; copper diacetate at 95℃; for 0.25h; Ullmann Condensation; Microwave irradiation;44%
1-amino-2-methyl-4-bromoanthraquinone
81-50-5

1-amino-2-methyl-4-bromoanthraquinone

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

C27H21N3O5S
1052088-32-0

C27H21N3O5S

Conditions
ConditionsYield
With potassium acetate; copper(II) acetate monohydrate; copper In methanol at 95℃; for 0.666667h; Ullmann Condensation; Microwave irradiation;42%
1-amino-2, 4-dibromoanthraquinone
81-49-2

1-amino-2, 4-dibromoanthraquinone

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

C26H18BrN3O5S

C26H18BrN3O5S

Conditions
ConditionsYield
With potassium acetate; copper diacetate In pentan-1-ol at 95℃; for 0.0833333h; Ullmann Condensation; Microwave irradiation;39%
1-amino-2-methyl-4-bromoanthraquinone
81-50-5

1-amino-2-methyl-4-bromoanthraquinone

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

sodium 1-amino-2-methyl-4-[4-phenylamino-3-sulfophenylamino]-9,10-dioxo-9,10-dihydroanthracene
1052088-02-4

sodium 1-amino-2-methyl-4-[4-phenylamino-3-sulfophenylamino]-9,10-dioxo-9,10-dihydroanthracene

Conditions
ConditionsYield
With copper at 120℃; for 0.0833333h; Ullmann reaction; aq. phosphate buffer; Microwave irradiation;30%
2,4,6-trinitrochlorobenzene
88-88-0

2,4,6-trinitrochlorobenzene

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

2-anilino-5-(2,4,6-trinitro-anilino)-benzenesulfonic acid

2-anilino-5-(2,4,6-trinitro-anilino)-benzenesulfonic acid

Conditions
ConditionsYield
With water; sodium acetate
2,4-dichloro-1,5-dinitrobenzene
3698-83-7

2,4-dichloro-1,5-dinitrobenzene

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

6,6'-dianilino-3,3'-(4,6-dinitro-m-phenylenediamino)-bis-benzenesulfonic acid

6,6'-dianilino-3,3'-(4,6-dinitro-m-phenylenediamino)-bis-benzenesulfonic acid

Conditions
ConditionsYield
With ethanol; sodium carbonate
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

2,6-dichloro-3,5-dinitrotoluene
51676-76-7

2,6-dichloro-3,5-dinitrotoluene

6,6'-dianilino-3,3'-(2-methyl-4,6-dinitro-m-phenylenediamino)-bis-benzenesulfonic acid

6,6'-dianilino-3,3'-(2-methyl-4,6-dinitro-m-phenylenediamino)-bis-benzenesulfonic acid

Conditions
ConditionsYield
With copper(I) sulfate; sodium carbonate; copper(II) sulfate
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

4-anilino-3-sulfo-benzenediazonium-betaine
46988-73-2

4-anilino-3-sulfo-benzenediazonium-betaine

Conditions
ConditionsYield
Diazotization;
Diazotization;
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

Conditions
ConditionsYield
With sulfuric acid
With hydrogenchloride; tin(ll) chloride
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

1-chloro-4,7-dinitro-10H-acridin-9-one
857612-92-1

1-chloro-4,7-dinitro-10H-acridin-9-one

2-anilino-5-(4,7-dinitro-9-oxo-9,10-dihydro-acridin-1-ylamino)-benzenesulfonic acid

2-anilino-5-(4,7-dinitro-9-oxo-9,10-dihydro-acridin-1-ylamino)-benzenesulfonic acid

Conditions
ConditionsYield
With sodium acetate; nitrobenzene
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

2-naphthol-6-sulfonic acid
93-01-6

2-naphthol-6-sulfonic acid

6-(4-anilino-3-sulfo-anilino)-naphthalene-2-sulfonic acid

6-(4-anilino-3-sulfo-anilino)-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
nach dem Sulfit-Verfahren;
4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

potassium-salt of/the/ 4-chloro-3,5-dinitro-benzenesulfonic acid-(1)

potassium-salt of/the/ 4-chloro-3,5-dinitro-benzenesulfonic acid-(1)

6-anilino-3',5'-dinitro-3,4'-imino-bis-benzenesulfonic acid

6-anilino-3',5'-dinitro-3,4'-imino-bis-benzenesulfonic acid

Conditions
ConditionsYield
With water; sodium acetate
sulfuric acid
7664-93-9

sulfuric acid

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

hydrogenchloride
7647-01-0

hydrogenchloride

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

tin dichloride

tin dichloride

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

4-aminodiphenylamine-2-sulfonic acid
91-30-5

4-aminodiphenylamine-2-sulfonic acid

4-(4,6-dichloro-[1,3,5]triazin-2-ylamino)-5-hydroxy-naphthalene-2,7-disulfonic acid
7538-88-7

4-(4,6-dichloro-[1,3,5]triazin-2-ylamino)-5-hydroxy-naphthalene-2,7-disulfonic acid

C25H17Cl2N7O10S3

C25H17Cl2N7O10S3

Conditions
ConditionsYield
Stage #1: 4-aminodiphenylamine-2-sulfonic acid With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 2h;
Stage #2: 4-(4,6-dichloro-[1,3,5]triazin-2-ylamino)-5-hydroxy-naphthalene-2,7-disulfonic acid With sodium carbonate In water at 5 - 15℃; for 2h; pH=6.5 - 7;
74.2 g

91-30-5Relevant articles and documents

Light-sensitive polycondensation product containing diazonium and dialdehyde groups, and light-sensitive recording material prepared therewith

-

, (2008/06/13)

A light-sensitive diazonium group-containing polycondensation product of a diazonium salt corresponding to the general formula STR1 wherein R1, R2, and R3 denote hydrogen atoms, halogen atoms, alkyl groups having 1 to 3 carbon atoms or alkoxy groups having 1 to 6 carbon atoms, and X denotes the anion of the diazonium salt, and an aldehyde selected from the group consisting of dialdehydes, acetals of dialdehyde hydrates, and esters of dialdehyde hydrates, a process for producing such a light-sensitive polycondensation product and a light-sensitive recording material comprising a layer support and a light-sensitive layer containing such a light-sensitive polycondensation product.

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