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Ionic Bicyclobutane as an Intermediate in the Reaction of PhS- with 3-Halobicyclobutanecarbonitrile: Comparison between Thio- and Oxycarbenium Ions
Hoz, Shmaryahu,Aurbach, Doron
, p. 3285 - 3291 (2007/10/02)
The nucleophilic reaction of PhS- with 3-chloro- and 3-bromobicyclobutanecarbonitrile (2-Cl(Br)) in MeOH and DME was investigated.The products in MeOH are the dithioketal 3 and the two cis-trans isomers of the thiooxoketal 4.The identity of the
