910659-14-2Relevant academic research and scientific papers
Synthesis of Secondary and Tertiary Alkyl Boronic Esters by gem-Carboborylation: Carbonyl Compounds as Bis(electrophile) Equivalents
Shi, Dunfa,Wang, Lu,Xia, Chungu,Liu, Chao
, p. 10318 - 10322 (2018)
An unprecedent gem-carboborylation of aldehydes and ketones provides access to various secondary and tertiary alkyl boronic esters. The addition of B2pin2 to a carbonyl compound generates α-oxyl-substituted alkyl boron species. Organ
Facile formation of β-hydroxyboronate esters by a Cu-catalyzed diboration/Matteson homologation sequence
Moore, Cameron M.,Medina, Casey R.,Cannamela, Peter C.,McIntosh, Melissa L.,Ferber, Carl J.,Roering, Andrew J.,Clark, Timothy B.
supporting information, p. 6056 - 6059 (2015/01/16)
The copper-catalyzed diboration of aldehydes was used in conjunction with the Matteson homologation, providing the efficient synthesis of β-hydroxyboronate esters. The oxygen-bound boronate ester was found to play a key role in mediating the homologation
Catalytic diboration of aldehydes via insertion into the copper-boron bond
Laitar, David S.,Tsui, Emily Y.,Sadighi, Joseph P.
, p. 11036 - 11037 (2007/10/03)
Mesitaldehyde reacts cleanly with (IPr)CuB(pin) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene); pin = 2,3-dimethyl-2,3-butanediolate] to afford the product complex 1, the first well-defined product of carbonyl group insertion into a metal-boron
