2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

• Chemical Name: 2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS No.: 910659-14-2
• Molecular Formula: C₁₉H₃₆B₂O₅
• Molecular Weight: 366.114
• Mol file: 910659-14-2.mol

Synonyms:2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property of 2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 1 articles about 2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

bis(pinacol)diborane (73183-34-3) + cyclohexanecarbaldehyde (2043-61-0) → 2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (910659-14-2)

Guidance literature:

(1,3-dicyclohexylimidazol-2-ylidene)copper(I) tert-butoxide; In benzene; 22 h at room temp.;

DOI:10.1021/ja064019z

Reference yield: 82.0%

2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (910659-14-2) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → (cyclohexyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)dimethyl(phenyl)silane (1512864-40-2)

Guidance literature:

With sodium t-butanolate; In toluene; at 100 ℃; for 6h; Temperature; Mechanism; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;

DOI:10.1021/jacs.7b02518

Reference yield: 60.0%

2-(cyclohexyl((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oxy)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (910659-14-2) + bis(pinacol)diborane (73183-34-3) → 2,2'-(cyclohexylmethylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (1512864-19-5)

Guidance literature:

With sodium t-butanolate; In toluene; at 100 ℃; for 6h; Temperature; Mechanism; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;

DOI:10.1021/jacs.7b02518

upstream raw materials:

bis(pinacol)diborane

cyclohexanecarbaldehyde

Downstream raw materials:

2,2'-(cyclohexylmethylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

(cyclohexyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)dimethyl(phenyl)silane