91083-80-6Relevant academic research and scientific papers
Palladium-catalyzed intermolecular Heck reaction of alkyl halides
Zou, Yinjun,Zhou, Jianrong
supporting information, p. 3725 - 3728 (2014/04/03)
Intermolecular Heck reaction of common alkyl halides, a longstanding problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf)Pd0 to alkyl halide initiated the catalytic cycle and gave alkyl radicals. This journal is the Partner Organisations 2014.
