91107-01-6Relevant academic research and scientific papers
SCISSION OF OXIRANES BY ACID ANHYDRIDES TO UNSATURATED ALCOHOL ESTERS
Gevorkyan, A.A.,Kazaryan, P.I.,Avakyan, S.V.,Simonyan, E.S.
, p. 254 - 257 (2007/10/02)
The reactions of some 1-R-3-methyl-2,3-epoxybutanes with acetic and propionic anhydrides takes place at 140-160 deg C, regioselectively, with the formation of β-metallyl alcohol esters.
New Routes to Substituted 1,3-Dienes, Allylic Alcohols, and α,β-Unsaturated Ketones
Brown, Roger S.,Eyley, Stephen C.,Parsons, Philip J.
, p. 438 - 439 (2007/10/02)
Phenylselenenyl chloride reacts with isoprene giving chloroselenides (1) and (2) which are converted by alkylation and subsequent oxidation into synthetically useful dienes, allylic alcohols, or α,β-unsaturated ketones.
ELECTROCHEMICAL PROCEDURE DIRECTED TO THE SELECTIVE RING OPENING OF EPOXIDES TO ALLYLIC ALCOHOLS
Uneyama, Kenji,Nisiyama, Noriyuki,Torii, Sigeru
, p. 4137 - 4138 (2007/10/02)
A transformation of epoxides 2 into allylic alcohols 1 was achieved by an electrogenerated acid-catalysis in ClCH2CH2Cl - TsONa - TsONEt4 - Pt system.
