911122-40-2Relevant academic research and scientific papers
Pyrazolyl-N-heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity
Page, Michael J.,Wagler, Joerg,Messerle, Barbara A.
experimental part, p. 7029 - 7038 (2010/01/06)
A series of bidentate 1-(1-pyrazolylmethyl)-substituted NHC ligands (13a-c, 14a-c and 15a-c) were synthesised with substituents of varying steric bulk incorporated adjacent to the donor atoms. These ligands were coordinated to rhodium(I) to give a series of complexes of the general formula [Rh(L)(COD)]BPh4 (where L = a mixed-donor pyrazolyl-NHC ligand and COD = 1,5-cyclooctadiene). The solid state structures of [Rh(13b)(COD)]BPh 4 (16b), [Rh(13c)(COD)]BPh4 (16c), [Rh(14a)(COD)]BPh 4 (17a), [Rh(14b)(COD)]BPh4 (17b), [Rh(15a) 2(COD)]BPh4 (18a), and [Rh(15b)(COD)]BPh4 (18b) were determined by single crystal X-ray diffraction. The complex [Rh(15a) 2(COD)]BPh4 (18a) is unusual in that two of the pyrazolyl-NHC ligands (15a) are coordinated to the metal through the NHC donor instead of one ligand forming the expected chelate. These complexes (with the exception of 18a) were found to be effective catalysts for the hydrogenation of styrene. The catalytic activity was correlated with complex structure, and it was found that the greater the steric bulk of the metal bound ligand, the slower the rate of the hydrogenation.
Rhodium(I) and iridium(I) complexes of pyrazolyl-N-heterocyclic carbene ligands
Messerle, Barbara A.,Page, Michael J.,Turner, Peter
, p. 3927 - 3933 (2007/10/03)
Several Rh(i) and Ir(i) complexes containing an N-heterocyclic carbene-pyrazolyl chelate ligand have been synthesised. Determination of the single-crystal X-ray structure of the Ir(i) complex showed a novel binding mode with the iridium centre coordinated to two ligands via two carbene donors in preference to one ligand forming the entropically favoured chelate. The hydrogenation activity of several of these complexes was investigated along with that of previously synthesised Rh(i) and Ir(i) complexes containing an analogous phosphine-pyrazolyl chelate. The Royal Society of Chemistry 2006.
