91146-08-6Relevant academic research and scientific papers
Hypervalent iodine induced nucleophilic additions to alkenes: Synthesis of 1,2-diperchlorates
De Mico, Antonella,Margarita, Roberto,Parlanti, Luca,Piancatelli, Giovanni,Vescovi, Andrea
, p. 16877 - 16882 (2007/10/03)
A novel iodine (III) reagent has been developed by the BAIB/Mg(CIO4)2 reagent combination. Reaction of this reagent with alkenes yielded 1,2- diperchlorates.
REACTION OF IODOSOFLUOROSULFATE WITH ALKENES
Zefirov, N. S.,Kasumov, T. M.,Koz'min, A. S.,Sorokin, V. D.,Polishchuk, V. R.
, p. 341 - 352 (2007/10/02)
The electrophilic addition of iodosofluorosulfate to a series of acyclic and mono-, bi-, and polycyclic olefins, dienes, and trienes was investigated for the first time. The high electrophilicity of this reagent favors the formation of the intermediate ca
IODOSOBENZENE TETRAFLUOROBORATE: FIRST EXAMPLE OF A STABLE ELECTROPHILIC HYPERVALENT IODINE REAGENT WITHOUT NUCLEOPHILIC LIGANDS
Zhdankin, Viktor V.,Tykwinski, Rik,Caple, Ronald,Berglund, Bruce,Koz'min, Anatoly S.,Zefirov, Nikolai S.
, p. 3717 - 3720 (2007/10/02)
Iodosobenzene tetrafluoroborate 1 has been prepared by the reaction of PhI(OAc2) and aqueous HBF4, and its reactions with alkenes, silyl enol ethers, and acetylenes have been studied.
NOVEL REAGENTS CONTAINING HYPERVALENT IODINE AND THEIR USE FOR ELECTROPHILIC ADDITIONS TO OLEFINS
Zefirov, Nikolai S.,Zhdankin, Viktor V.,Dan'kov, Yu. V.,Caple, Ronald,Berglund, Bruce A.
, p. 3971 - 3974 (2007/10/02)
A series of novel I(III) containing reagents have been developed and their electrophilic reactions with olefins giving vic-disubstituted derivatives (including vic-ditriflates) are described.
