912275-84-4Relevant articles and documents
Novel fluorescent perylene liquid crystal with diphenylacrylonitrile groups: Observation of a large pseudo stokes shift based on AIE and FRET effects
Zhu, Mingguang,Zhuo, Youzhen,Cai, Kaicong,Guo, Hongyu,Yang, Fafu
, p. 343 - 349 (2017)
A novel perylene liquid crystal with diphenylacrylonitrile groups on 1,7-bay positions was synthesized in high yield. This highly decorated perylene bisimide showed the ordered hexagonal columnar liquid crystalline behaviour between 124.9 and 189.5 °C. Up
Novel perylene columnar liquid crystal tuned by azo isomerization on bay-positions
Lin, Jianrong,Ji, Xiaoyu,Guo, Hongyu,Yang, Fafu
, (2019/07/04)
Two azo-perylene derivatives (PBI-AZO-1 and PBI-AZO-2) with two alkyl chains and six alkoxy chains were designed and synthesized in yield of 63% and 49%, respectively. PBI-AZO-1 showed no mesophase but PBI-AZO-2 exhibited ordered hexagonal columnar mesophase based on the favorable effects of multiple alkyl chains. PBI-AZO-1 and PBI-AZO-2 exhibited the cis and trans azo-isomerization under radiation of UV light and the fluorescence quantum yields enhanced remarkably from 0.61 and 0.64 to 0.78 and 0.88, respectively. The ordered hexagonal columnar mesophase of PBI-AZO-2 was destroyed by isomerization due to the influence of asymmetrical mixture of cis and trans isomers. The transformation of liquid crystal/non-liquid crystal of PBI-AZO-2 before and after cis/trans isomerization displayed good reversibility by storing the sample for 15 days at room temperature. This kind of liquid crystallic behavior tuned by azo isomerization was first observed for perylene liquid crystal.
Preparation method and application for amphiphilic naphthoyl diimide gelator
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Paragraph 0031; 0034; 0036; 0038, (2018/04/02)
The invention belongs to the technical field of supramolecular chemistry, and specifically relates to a preparation method and an application for an amphiphilic naphthoyl diimide gelator. The amphiphilic naphthoyl diimide gelator provided by the invention has a molecular formula of C89H138N4O21, and can enable benzene, toluene, xylene, dimethyl sulfoxide (DMSO) or a tetrahydrofuran solution with awater content of 30% (H2O-THF with a concentration of 30%) to generate gelation at a low concentration (3.3 mg.mL to 9.5 mg.mL through a heating-cooling method. Meanwhile, the molecular gel formed by gelation can realize reversible conversion between a solution state and a gel state through the external action of heating-cooling. The gelator provided by the invention has the advantages ofsimple synthesis, easily modified structure, thermal reversibility, large polarity range of a gelated solvent, etc., and has potential application values in fields like catalysis, sensor technologies, drug delivery and chiral separation.