91247-60-8

Basic information

• Product Name: 1-methoxy-2-nitro-4-(tert-butyl)benzene
• Synonyms: 1-methoxy-2-nitro-4-(tert-butyl)benzene
• CAS NO: 91247-60-8
• Molecular Weight: 209.245
• Mol File: 91247-60-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-methoxy-2-nitro-4-(tert-butyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-2-nitro-4-(tert-butyl)benzene(91247-60-8)
• EPA Substance Registry System: 1-methoxy-2-nitro-4-(tert-butyl)benzene(91247-60-8)

Safety Data

• Hazardous Substances Data: 91247-60-8(Hazardous Substances Data)

Upstream product

• 5396-38-3 1-(tert-butyl)-4-methoxybenzene 
• 22385-83-7 4-t-butyl-1,2-dinitrrobenzene 
• 124-41-4 sodium methylate 
• 3279-07-0 4-tert-butyl-2-nitrophenol 
• 77-78-1 dimethyl sulfate 
• 186581-53-3 diazomethane 

Downstream Products

• 51-28-5 2,4-Dinitrophenol 
• 536723-91-8 N-(5-tert-butyl-2-methoxy-phenyl)-hydroxylamine 
• 3535-88-4 5-tert-butyl-2-methoxyaniline 

Relevant articles and documents

Direct nitration method of electron-enriched aromatic hydrocarbons

The invention discloses a direct nitration method of electron-enriched aromatic hydrocarbons, and belongs to the field of organic synthesis. The direct nitration method is a novel green free radical nitration method; aromatic hydrocarbons are taken as raw materials, acetonitrile, dichloromethane, chloroform, or acetone is taken as a reaction solvent, at room temperature conditions, the raw materials and green nitration reagent tert-butyl nitrite (TBN) are subjected to free radical nitration so as to obtain nitro-aromatic compounds. According to the direct nitration method, no metal is adoptedin reaction, tert-butyl nitrite is directly adopted in nitration reaction. Electron-donating groups such as OMe are introduced, the electron density of aromatic compounds is increased, the nitration reaction possibility is increased. The using amount of tert-butyl nitrite is reduced; only a product and tert-butyl alcohol are generated, environment pollution is reduced. The direct nitration methodis promising in application prospect in the field of nitro-aromatic compound synthesis, green nitration is realized, and a novel idea is provided for large-scale industrialized nitro-aromatic compoundproduction.

Convenient Nitration of Anisole and its Derivatives using an NO-O2 System

Anisole and its derivatives are regioselectively nitrated by use of nitrogen monoxide-molecular dioxygen mixed gas under mild conditions.

Interaction between Electron Donor and Acceptor Groups in Some Trisubstituted Benzenes. Part 1. Relative Reactivities of 4-Substituted 1,2-Dinitrobenzenes towards Sodium Methoxide

In an effort to study the effects of 'through conjugation' on the properties of some 1,2,4-trisubstituted benzenes, the rates of reaction of a series of four 4-substituted 1,2-dinitrobenzenes with sodium methoxide in methanol have been studied.Although reactivities at the 2-position were qualitatively in the order to be expected from inductive effects, those at the 1-position were highly sensitive to the influence of mesomeric donor action of the 4-substituent.Relatively large effects were seen for the 4-alkyl derivatives; and C-H hyperconjugation appeared to be stronger than C-C hyperconjugation.