91270-72-3Relevant academic research and scientific papers
Ni-Catalyzed C-P Coupling of Aryl, Benzyl, or Allyl Ammonium Salts with P(O)H Compounds
Yang, Bo,Wang, Zhong-Xia
, p. 1500 - 1509 (2019)
A methodology that allows for the construction of C-P bonds via the nickel-catalyzed cross-coupling of organoammonium salts with appropriate phosphorus nucleophiles has been developed. Aryl-, pyridyl-, benzyl-, and allyl-ammonium triflates can be employed as the electrophiles. The employed phosphorus-based nucleophiles included diaryl/dibutyl phosphine oxide, dialkyl phosphonates, and ethyl phenylphosphinate. Functional groups OMe, CN, CF3, F, Cl, C(O)NMe2, and C(O)tBu were tolerated.
Phosphororganische Verbindungen 106. Die Synthese Optisch Aktiver Tertiaerer Phosphine und Phosphinoxide mit Ortho-Substituierten Arylliganden
Horner, L.,Simons, G.
, p. 77 - 90 (2007/10/02)
Compounds of the type C6H5Y (Y=OR, -NMe2), are lithiated with n-butyllithium (n-BuLi) in the ortho-position according (1) and transformed by special reactions to compounds of the type I and II. The representatives 7-22 of the type I with Y=OR ar
