913648-53-0Relevant academic research and scientific papers
1,4-Addition of arylboronic acids to β-aryl-α,β-unsaturated ketones and esters catalyzed by a rhodium(I)-chiraphos complex for catalytic and enantioselective synthesis of selective endothelin A receptor antagonists
Itoh, Takahiro,Mase, Toshiaki,Nishikata, Takashi,Iyama, Tetsuji,Tachikawa, Hiroto,Kobayashi, Yuri,Yamamoto, Yasunori,Miyaura, Norio
, p. 9610 - 9621 (2007/10/03)
An enantioselective synthesis of acyclic β-diaryl ketones and esters via 1,4-addition of arylboronic acids to β-aryl-α,β-unsaturated ketones or esters is described. The complex in situ prepared from [Rh(nbd)2]BF4 and chiraphos was fo
