91388-23-7

Basic information

• Product Name: Phenoxymethyl-triphenyl-phosphoniumchlorid
• CAS NO: 91388-23-7
• Molecular Weight: 404.876
• Mol File: 91388-23-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenoxymethyl-triphenyl-phosphoniumchlorid(CAS DataBase Reference)
• NIST Chemistry Reference: Phenoxymethyl-triphenyl-phosphoniumchlorid(91388-23-7)
• EPA Substance Registry System: Phenoxymethyl-triphenyl-phosphoniumchlorid(91388-23-7)

Safety Data

• Hazardous Substances Data: 91388-23-7(Hazardous Substances Data)

Upstream product

• 33837-96-6 methyl thiomethyl ether of phenol 
• 108-95-2 phenol 
• 6707-01-3 (chloromethoxy)benzene 
• 603-35-0 triphenylphosphine 

Downstream Products

• 1615240-67-9 3-bromo-β-phenoxystyrene 
• 91969-45-8 (2,2-Dimethyl-cyclopropyl)-phenyl-ether 
• 112586-75-1 (3,4,4,4-Tetrafluoro-3-heptafluoropropyloxy-but-1-ynyloxy)-benzene 
• 112586-74-0 Heptafluoropent-1-ynyloxy-benzene 
• 112586-73-9 Pentafluorobut-1-ynyloxy-benzene 
• 104670-67-9 (Phenoxymethylene)triphenylphosphorane 
• 5820-20-2 ((2-methylprop-1-en-1-yl)oxy)benzene 
• 39153-68-9 (E,Z)-β-phenoxystyrene 
• 97023-20-6 Phenoxymethylen-cyclohexan 
• 67774-21-4 phenyl 1,1-diphenylvinyl ether 

Relevant articles and documents

Diarylrhodates as promising active catalysts for the arylation of vinyl ethers with grignard reagents

Anionic diarylrhodium complexes, generated by reacting [RhCl(cod)] 2 with 2 equiv of aryl Grignard reagents, were found to be effective active catalysts in cross-coupling reactions of vinyl ethers with aryl Grignard reagents, giving rise to the production of vinyl arenes. In this catalytic system, vinyl-O bonds were preferably cleaved over Ar-O or Ar-Br bonds. A lithium rhodate complex was isolated, and its crystal structure was determined by X-ray crystallography.