33837-96-6

Basic information

• Product Name: Benzene, [(methylthio)methoxy]-
• CAS NO: 33837-96-6
• Molecular Formula: C8H10OS
• Molecular Weight: 154.233
• Mol File: 33837-96-6.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [(methylthio)methoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(methylthio)methoxy]-(33837-96-6)
• EPA Substance Registry System: Benzene, [(methylthio)methoxy]-(33837-96-6)

Safety Data

• Hazardous Substances Data: 33837-96-6(Hazardous Substances Data)

Upstream product

• 67-68-5 dimethyl sulfoxide 
• 108-95-2 phenol 
• 110-89-4 piperidine 
• 34619-03-9 tert-butyldicarbonate 
• 74-86-2 acetylene 
• 100-66-3 methoxybenzene 
• 2373-51-5 chloro-methylsulfanyl-methane 

Downstream Products

• 1615240-67-9 3-bromo-β-phenoxystyrene 
• 91388-23-7 Phenoxymethyl-triphenyl-phosphoniumchlorid 
• 864754-50-7 C₁₄H₂₁BO₃S 
• 269409-97-4 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 
• 92496-20-3 (3-phenoxyprop-1-yn-1‐yl)benzene 
• 1327239-53-1 N-methyl-N-(phenoxymethoxy)acetamide 
• 1746-13-0 allyl phenyl ether 
• 2050-04-6 (pentyloxy)benzene 
• 110181-06-1 C₁₄H₁₄N₂O₄ 
• 39213-30-4 Phenoxymethyl-methylsulfon 
• 6707-01-3 (chloromethoxy)benzene 
• 87453-27-8 fluoromethyl phenyl ether 

Relevant articles and documents

Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives

An iridium-catalyzed ortho-selective C-H borylation of phenol and aniline derivatives has been successfully developed. Iridium/bipyridine-catalyzed C-H borylation generally occurred at the meta- and para-positions of aromatic substrates. Introduction of an electron-withdrawing substituent on the bipyridine-type ligand and a methylthiomethyl group on the hydroxy and amino groups of the phenol and aniline substrates, however, dramatically altered the regioselectivity, affording exclusively ortho-borylated products. The reaction proceeded in good to excellent yields with good functional group tolerance. C-H borylation was applied to the synthesis of a calcium receptor modulator.

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Expanded substrate scope and improved reactivity of ether-forming cross-coupling reactions of organotrifluoroborates and acetals

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