913975-58-3

Upstream product

• 251571-56-9 [(S)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-methanol 
• 123-11-5 4-methoxy-benzaldehyde 
• 6228-47-3 n-propyltriphenylphosphonium bromide 
• 927396-40-5 (S)-2-(4-methoxy-phenyl)-[1,3]dioxane-4-carbaldehyde 

Downstream Products

• 913975-59-4 (3S,Z)-3-(4-methoxybenzyloxy)hept-4-en-1-ol 
• 913975-67-4 (3S,Z)-tetrahydropyran-2-yloxy-3-(2,2,2-trimethyl-1,1-diphenyldisilyloxy)hept-4-ene 
• 913975-60-7 2-[(3S,Z)-3-(4-methoxybenzyloxy)hept-4-enyloxy]tetrahydro-2H-pyran 

Relevant academic research and scientific papers

Remote control of diastereoselectivity in intramolecular reactions of chiral allylsilanes

During investigations of cyclization reactions between chiral allylsilanes and N-acyliminium ions, it was discovered that a suitably positioned benzyloxy group on the allylsilane component caused a reversal in the diastereoselectivity of these reactions r