91418-99-4Relevant academic research and scientific papers
Stereoselective and Regioselective Pinacol-Type Rearrangement of a Fused Bicyclic Oxetanol Scaffold
Melis, Nicola,Luridiana, Alberto,Guillot, Régis,Secci, Francesco,Frongia, Angelo,Boddaert, Thomas,Aitken, David J.
, p. 5896 - 5902 (2017/10/31)
The Paternò-Büchi reaction between benzaldehyde and trimethylsilyloxycyclopentene gave access to an unprecedented silyl ether derivative of 6-oxabicyclo[3.2.0]heptan-1-ol. The bicyclic structure underwent selective reductive ring opening and acid-catalyzed pinacol-type rearrangement reactions with complete regioselectivity, accompanied by moderate to excellent mechanism-dependent diastereoselectivity.
Stereoselective Epoxidation of 3-trans-Benzylideneisoborneol
Sanghvi, Y. S.,Rao, A. S.
, p. 317 - 320 (2007/10/02)
2-Benzylidenecyclopentanol (2) can be epoxidized stereoselectively to furnish 2-trans-benzylidene-1β-hydroxycylopentane β-oxide (4) with either t-butyl hydroperoxide in the presence of vanadium catalyst or m-chloroperoxybenzoic acid.Epoxidation of 3-trans
