915149-82-5

Basic information

• Product Name: 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal
• Synonyms: 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal
• CAS NO: 915149-82-5
• Molecular Weight: 478.223
• Mol File: 915149-82-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal(915149-82-5)
• EPA Substance Registry System: 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal(915149-82-5)

Safety Data

• Hazardous Substances Data: 915149-82-5(Hazardous Substances Data)

Upstream product

• 915149-80-3 (2R,3R)-2,3-dibenzyl-1,4-dioxaspiro[4.4]non-7-ene 
• 75-25-2 Bromoform 
• 915149-78-9 (2R,3R)-2,2-diallyl-4,5-dibenzyl-[1,3]dioxolane 
• 300-57-2 allylbenzene 
• 2883-45-6 1, 6-heptadien-4-ol 
• 53859-89-5 vinylmethyl ketone 
• 1142-22-9 (E)-1,4-diphenylbut-2-ene 
• 18069-22-2 (2R,3R)-1,4-diphenylbutane-2,3-diol 

Downstream Products

• 915222-05-8 (2'R,3'R,7'S)-3-{8'-bromo-2',3'-dibenzyl-1',4'-dioxaspiro[4.5]dec-8'-en-7'-yl}indole 
• 915149-84-7 (2'R,3'R,7'R)-3-{8'-bromo-2,3-dibenzyl-1',4'-dioxaspiro[4.5]dec-8'-en-7'-yl}indole 

Relevant articles and documents

Concise assembly of the polycyclic frameworks associated with the hapalindole and fischerindole alkaloids

Reaction of N-methylindole (4) with 6,6-dibromobicyclo[3.1.0]hexane (5) in the presence of silver tetrafluoroborate affords conjugate 7 in 67% yield. This product can be readily elaborated to compounds 12b and 13b which embody the polycyclic frameworks as