91562-27-5

Usage

General Description

2-(But-3-en-1-yl)-N,N-diMethylaniline is a chemical compound with the chemical formula C15H23N. It is a yellow liquid with a strong odor and is insoluble in water. 2-(But-3-en-1-yl)-N,N-diMethylaniline is commonly used as an intermediate in the synthesis of various organic compounds and has applications in the pharmaceutical and agrochemical industries. It is also used as a dye and pigment intermediate. 2-(But-3-en-1-yl)-N,N-diMethylaniline is considered to be hazardous if ingested, inhaled, or in contact with skin, and proper safety precautions should be taken when handling this chemical.

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 22608-37-3 ortho-lithio-N,N-dimethylaniline 
• 6992-97-8 2-(but-3-en-1-yl)aniline 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 

Downstream Products

• 767-58-8 1-methylindane 
• 1224956-14-2 C₃₀H₁₇BF₁₅N 

Relevant academic research and scientific papers

Palladium-mediated intramolecular C-N bond formation between tertiary amines and alkenes

The reaction of terminal alkenylarenes having either o-(dimethylamino) or o-[(dimethylamino)methyl] substituents with PdCl2(MeCN)2 in MeOH in the presence of NaOAc and PPh3 has been studied. This reaction affords allylic p

Photosolvolysis of 2-Allylated Anilines to 2-Indanols

It is shown that 2-allylated anilines (cf.Schemes 2-4,7, and 8) on irradiation in protic solvents such as H2O.MeOH, and EtOH in the presence of H2SO4 undergo a novel photosolvolysis reaction to yield specifically trans-2-hydroxy- and trans-2-alkoxy-1-methylindanes.Intermediates are presumably tricyclo1,8>nona-2,4-dienes formed in an intramolecular cycloaddition reaction (cf.Scheme 7).On the other hand, N,N,N-trimethyl-2-(1'-methylallyl)anilinium salts 18 (Scheme 6) and 2-(3'-butenyl)-N,N-dimethylaniline (17) lose on irradiation in MeOH or H2SO4/MeOH the ammonium group reductively to yield (1-methylallyl)benzene (19) and 1-methylindane (20), respectively.