915696-34-3Relevant academic research and scientific papers
Cyclization reactions of homopropargyl azide derivatives catalyzed by PtCl4 in ethanol solution: Synthesis of functionalized pyrrole derivatives
Hiroya, Kou,Matsumoto, Shigemitsu,Ashikawa, Masayasu,Ogiwara, Kentaro,Sakamoto, Takao
, p. 5349 - 5352 (2006)
PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives to pyrrole rings were investigated. Using ethanol as solvent with 2,6-di-tert-butyl-4-methylpyridine as the base was found to be the best set of conditions for effecting this ring-closing reaction. These reaction conditions can be applied to the preparation of functionalized pyrrole derivatives, with no effect on the functional groups.
