91574-95-7Relevant academic research and scientific papers
Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
Yoshida,Shinke,Kawano,Takaki
supporting information, p. 10616 - 10619 (2015/06/30)
A variety of branched alkenylstannanes can directly be synthesized with excellent α-selectivity by the copper-catalyzed hydrostannylation using a distannane or a silylstannane, irrespective of the electronic and steric characteristics of terminal alkynes employed. Synthetic utility of the resulting branched alkenylstannane has been demonstrated by the total synthesis of bexarotene.
Photochemical Properties of cis- and trans-1,2-Diphenylethyltrimethyltin(IV) and cis-1,2-Diphenylpropenyltrimethyltin(IV): Organometallic Derivatives of Stilbene
Kelly, John M.,Trautman, Raymond J.
, p. 909 - 914 (2007/10/02)
Upon direct u.v. irradiation in cyclohexane, benzene, alcohol, or chloroform slution, (1) undergoes cis-trans isomerisation about the olefin double bond as the only reaction.No evidence has been found for either homolytic or heterolytic
