916977-11-2

Upstream product

• 293732-19-1 (4,5-dimethoxy-2-iodophenyl)methyl bromide 
• 110451-87-1 2-bromomethyl-1-iodo-4,5-dimethoxybenzene 

Downstream Products

• 916977-18-9 methyl 7-(2-iodo-4,5-dimethoxybenzyl)-1-trimethylsiloxybicyclo[4.1.0]heptane-7-carboxylate 
• 1160714-65-7 N-(2-iodo-4,5-dimethoxybenzyl)-2-(2-methyl-1,3-dioxolan-2-yl)-1-(trimethylsilyl)-N-((trimethylsilyl)methyl)ethanamine 
• 916977-23-6 methyl 7-(4,5-dimethoxy-2-vinylbenzyl)-1-trimethylsiloxybicyclo[4.1.0]heptane-7-carboxylate 

Relevant academic research and scientific papers

Benzannulated cyclooctanol derivatives by samarium diiodide induced intramolecular carbonyl-alkene coupling - Scope, limitations, stereoselectivity

A series of γ-oxo esters 27-34 was prepared from methyl 2-silyloxycyclopropanecarboxylates 1-9 as key building blocks in a flexible modular synthesis. Their samarium diiodide promoted cyclization to benzannulated cyclooctanol derivatives was systematicall