
Tetrahedron Letters p. 2035 - 2038 (1984)
Update date:2022-08-05
Topics:
Kay, I.Trevor
Bartholomew, David
The acid catalysed rearrangement of an acetal derived from 2-hydroxymethyl-3-butene-1-ol proceeding via an intramolecular cation-olefin cyclisation provides acces to a 4-hydroxytetrahydropyran and thence to (+/-)-talaromycin B.
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