917499-87-7

Basic information

• Product Name: Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
• Synonyms: Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
• CAS NO: 917499-87-7
• Molecular Formula: C₈H₁₆O₁₀Rh₂
• Molecular Weight: 460
• EINECS: 240-084-8
• Mol File: 917499-87-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)(917499-87-7)
• EPA Substance Registry System: Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)(917499-87-7)

Safety Data

• Hazardous Substances Data: 917499-87-7(Hazardous Substances Data)

Upstream product

• 61-19-8 5'-adenosine monophosphate 
• 4578-31-8 adenosine-5'-monophosphate disodium salt 
• 64-19-7 acetic acid 
• 25776-14-1 H₁₆N₅Rh⁽²⁺⁾ 

Relevant articles and documents

Kinetics of the Reduction of a Tetra-μ-acetato-dirhodium Cation by Substituted 1,2- and 1,4-Dihydroxybenzene Compounds in Aqueous Perchlorate Media

The kinetics of the reduction of the tetra-μ-acetato-dirhodium cation, +(+), by substituted 1,2- and 1,4-dihydroxybenzene compounds (H2Q) have been investigated in aqueous perchlorate media.The observed rate equation (below) is interpreted in terms of a rate- -d+>/dt=2(k1+k2K1/+>)+> determining one-electron oxidation of H2Q or HQ- to a semiquinone radical intermediate.The rate constants for the cross-reactions are correlated with the semiquinone reduction potentials by means of the Marcus relationship.Self-exchange rate constants for the dihydroxybenzene/semiquinone and semiquinone/quinone couples are discussed in terms of the inner-sphere and solvent reorganization energies for electron exchange.