91767-65-6

Basic information

• Product Name: ethyl 2-chloro-3-hydroxy-3-phenylbutanoate
• CAS NO: 91767-65-6
• Molecular Formula: C₁₂H₁₅ClO₃
• Molecular Weight: 242.6987
• Mol File: 91767-65-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 370.9°C at 760 mmHg
• Flash Point: 178.1°C
• Density: 1.202g/cm³
• Vapor Pressure: 3.72E-06mmHg at 25°C
• Refractive Index: 1.526
• CAS DataBase Reference: ethyl 2-chloro-3-hydroxy-3-phenylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-chloro-3-hydroxy-3-phenylbutanoate(91767-65-6)
• EPA Substance Registry System: ethyl 2-chloro-3-hydroxy-3-phenylbutanoate(91767-65-6)

Safety Data

• Hazardous Substances Data: 91767-65-6(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 535-15-9 ethyl 1,1-dichloroacetate 
• 60-29-7 diethyl ether 

Downstream Products

• 1575-47-9 4-phenyl-5H-furan-2-one 
• 127229-82-7 Ethyl 2-chloro-3-phenyl-2-butenoate 
• 77-83-8 fraeseol 

Relevant articles and documents

α-Bromo-, α-chloro-, and α-trimethylsilyl-zinc ester enolates. New and universal Reformatsky-type Darzens and Peterson reactions

Low temperature reactions of ethyl dihaloacetates with carbonyl compounds in the presence of zinc/silver-graphite give α-halo-β-hydroxyalkanoates, which are readily converted into glycidates by base.Unser the same conditions ethyl(bromo)(trimethylsilyl) acetate with aldehydes and ketones forms α,β-unsaturated esters by a Reformatsky-Peterson reaction combination.