917894-72-5Relevant academic research and scientific papers
Designing Synergistic Nanocatalysts for Multiple Substrate Activation: Interlattice Ag-Fe3O4 Hybrid Materials for CO2-Inserted Lactones
Rajesh, U. Chinna,Losovyj, Yaroslav,Chen, Chun-Hsing,Zaleski, Jeffrey M.
, p. 3349 - 3359 (2020/03/05)
Multimetallic architectures that combine chemically diverse materials to affect tandem reactions within a single scaffold drive future nanocatalyst development. Here, we show the unique, interlattice growth of the small molecule activating Ag guest within
Silver-catalyzed one-pot synthesis of arylnaphthalene lactones
Eghbali, Nicolas,Eddy, Jennifer,Anastas, Paul T.
, p. 6932 - 6935 (2008/12/22)
(Chemical Equation Presented) Arylnaphthalene lignan lactones are valuable natural products with promising anticancer and antiviral properties. In an effort to simplify their synthesis, we investigated a one-pot multicomponent coupling reaction between phenylacetylene, carbon dioxide, and 3-bromo-1-phenyl-1-propyne. After the corresponding 1,6-diyne was generated in situ, cyclization afforded the desired product. The level of regioselectivity was enhanced through the tuning of electronic properties. The use of cinnamyl bromide which led to the formation of a 1,6-enyne intermediate was also studied.
Synthesis of 1,1′-binaphthyls by photo-dehydro-Diels-Alder reactions
Wessig, Pablo,Mueller, Gunnar
, p. 4524 - 4526 (2008/09/18)
1,1′-Binaphthyls are prepared by a conceptually novel approach based on the photo-dehydro-Diels-Alder reaction. The Royal Society of Chemistry 2006.
