918154-55-9Relevant academic research and scientific papers
An approach to the synthesis and assignment of the absolute configuration of all enantiomers of ethyl hydroxy(phenyl)methane(P-phenyl)phosphinate
Majewska, Paulina,Kafarski, Pawel,Lejczak, Barbara,Bryndal, Iwona,Lis, Tadeusz
, p. 2697 - 2701 (2006)
Ethyl butyryloxy(phenyl)methane(P-phenyl)phosphinate was hydrolyzed using four bacterial species as biocatalysts. In all cases the reaction was stereoselective and isomers bearing an α-carbon atom with an (S)-configuration were hydrolyzed preferentially.
The new way to synthesize ethyl 1-butyryloxy-1-phenylmethane(P-phenyl)phosphinate and whole-cell biocatalysis by Escherichia coli and Pseudomonas fluorescens
Majewska, Paulina
, p. 1048 - 1053 (2019/05/01)
A new compound, ethyl 1-carboxy-1-hydroxy-1-phenylmethane(P-phenyl)phosphinate, was synthesized and the configuration of its diastereoisomers was described using NMR spectroscopy. Acylation with butyryl chloride gave an unexpected product, ethyl butyrylox
Enzymatic resolution of ethyl α-hydroxyphosphinates in a modified reaction environment
Majewska, Paulina,Lejczak, Barbara,Kafarski, Pawel
experimental part, p. 1915 - 1920 (2010/11/18)
The enzymatic resolutions of two racemic ethyl hydroxyalkane(P-phenyl) phosphinates were performed by both esterification and hydrolysis approaches. The first reaction was performed in anhydrous diisopropyl ether with triethylamine or pyridine as additive
