918163-02-7Relevant articles and documents
Copper-catalyzed synthesis of N-aryl and N-sulfonyl indoles from 2-vinylanilines with O2 as terminal oxidant and TEMPO as cocatalyst
Liwosz, Timothy W.,Chemler, Sherry R.
supporting information, p. 335 - 339 (2015/02/19)
A copper-catalyzed intramolecular alkene oxidative amination that utilizes TEMPO as cocatalyst and O2 as the terminal oxidant has been developed. The method furnishes N-aryl and N-sulfonyl indoles from N-aryl and N-sulfonyl 2-vinylanilines, res
A visible-light-mediated oxidative C-N bond formation/aromatization cascade: Photocatalytic preparation of N-arylindoles
Maity, Soumitra,Zheng, Nan
supporting information, p. 9562 - 9566 (2012/11/07)
Just add light and air: Structurally diverse N-arylindoles can be prepared from readily prepared o-styryl anilines through visible-light photocatalysis. The reaction, which is conducted open to air, is mediated by [Ru(bpz) 3](PF6)2 (bpz=2,2'-bipyrazine) and involves both C-N bond formation and aromatization (see scheme). Using suitably substituted substrates, a 1,2-carbon shift can be also incorporated into this cascade reaction. Copyright
Synthesis of 1-aryl-1H-indole derivatives by iodine-mediated cyclization of 2-(arylamino)styrene derivatives
Kobayashi, Kazuhiro,Miyamoto, Kazuna,Yamase, Tohru,Nakamura, Daizo,Morikawa, Osamu,Konishi, Hisatoshi
, p. 1580 - 1584 (2007/10/03)
A convenient synthetic method for 1-aryl-1H-indole derivatives has been developed. 2-(Arylamino)-α-methylstyrene derivatives were treated with iodine in the presence of sodium hydrogencarbonate to give 1-aryl-3-methyl-1H- indole derivatives in fair to goo
