918309-79-2Relevant academic research and scientific papers
Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxides
Nemoto, Tetsuhiro,Sakamoto, Tatsurou,Matsumoto, Takayoshi,Hamada, Yasumasa
, p. 8737 - 8740 (2007/10/03)
An Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxide is described. Asymmetric allylic amination of terminal allylic carbonates proceeded in the presence of 2 mol % of Ir catalyst, 2 mol % of chiral diaminophosphine oxide, 5 mol % of NaPF6, and BSA, affording the chiral branched allylic amines in up to 95% ee.
