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• 4701-17-1 5-bromo-2-thiophencarboxaldehyde 
• 38257-52-2 4-(N,N-diphenylamino)iodobenzene 
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• 201802-67-7 4-(diphenylamino)phenyl boronic acid 
• 1309674-19-8 2-bromo-5-[4-(N,N-diphenylamino)phenyl]thiophene 
• 58268-08-9 2-(2-thienyl)-1,3-dioxolane 
• 1379771-83-1 C₃₄H₂₈N₂O₂S₂ 
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• 1194043-96-3 N,N-diphenyl-4-(5-(thiophen-2-yl)thiophen-2-yl)benzenamine 
• 762269-61-4 5′-(4-(diphenylamino)phenyl)(2,2′-bithiophene)-5-carboxaldehyde 

Relevant academic research and scientific papers

Rapid Synthesis of Thiophene-Based, Organic Dyes for Dye-Sensitized Solar Cells (DSSCs) by a One-Pot, Four-Component Coupling Approach

This one-pot, four-component coupling approach (Suzuki-Miyaura coupling/C-H direct arylation/Knoevenagel condensation) was developed for the rapid synthesis of thiophene-based organic dyes for dye-sensitized solar cells (DSSCs). Seven thiophene-based, org

Elucidating the structure-property relationships of donor-π-acceptor dyes for dye-sensitized solar cells (DSSCs) through rapid library synthesis by a one-pot procedure

The creation of organic dyes with excellent high power conversion efficiency (PCE) is important for the further improvement of dye-sensitized solar cells. We wish to describe the rapid synthesis of a 112-membered donor-π-acceptor dye library by a one-pot procedure, evaluation of PCEs, and elucidation of structure-property relationships. No obvious correlations between ε, and the η were observed, whereas the HOMO and LUMO levels of the dyes were critical for η. The dyes with a more positive EHOMO, and with an ELUMOsc, and it was the most important parameter for a high η. The above criteria of EHOMO and E LUMO should be useful for creating high PCE dyes; nevertheless, that was not sufficient for identifying the best combination of donor, π, and acceptor blocks. Combinatorial synthesis and evaluation was important for identifying the best dye. Combinatorial chemistry: A 112-membered donor-π-acceptor dye library was rapidly constructed by a one-pot, three-component coupling procedure (see scheme, SM=Suzuki-Miyaura). The evaluation of absorption spectroscopic and electrochemical measurements of all synthesized dyes, and cell performances of the selected 54 dyes were performed. The dyes with a more positive EHOMO, and with an E LUMO-0.80 V, exerted higher power conversion efficiencies.

An iterative approach to the synthesis of thiophene-based organic dyes

We developed an iterative synthetic method for oligo-aryl compounds using an organosilicon-based palladium-catalyzed cross-coupling reaction. Aryl compounds containing a benzyloxy(diisopropyl)silyl group (masked Si group) had sufficient chemical stability, and the unmasking step proceeded in a high yield under mild conditions. Both of the key unmasking/coupling steps required no strict anhydrous or degassed conditions. The developed procedure was used for the synthesis of thiophene-based organic dyes for dye-sensitized solar cells.