91860-99-0Relevant academic research and scientific papers
THE SYNTHESIS AND OSMYLATION OF 7,8-DIDEOOXY-1,2:3,4-DI-O-ISOPROPYLIDENE-Β-L-glycero-D-galacto-OCT-7-ENOPYRANOSE AND RELATED STUDIES
Brimacombe, John S.,Kabir, Abul K. M. S.
, p. 37 - 46 (2007/10/02)
A stereocontrolled route to 7,8-dideoxy-1,2:3,4-di-O-isopropylidene-β-L-glycero-D-galacto-oct-7-enopyranose (8) has been developed from 6,7-anhydro-1,2:3,4-di-O-isopropylidene-β-L-erythro-D-galacto-octopyranose (15), in which the final and key step involv
Chelation-Controlled Facially Selective Cyclocondensation Reactions of Chiral Alkoxy Aldehydes: Syntheses of a Mouse Androgen and of a Carbon-Linked Disaccharide
Danishefsky, Samuel J.,Pearson, William H.,Harvey, Daniel F.,Maring, Clarence J.,Springer, James P.
, p. 1256 - 1268 (2007/10/02)
Magnesium bromide in tetrahydrofuran catalyzes the cycloaddition of a variety of chiral alkoxy aldehydes with activated butadienes.The stereochemistry of these products is such that they can be rationalized as arising from a reacting conformer in which th
