91871-10-2Relevant academic research and scientific papers
Visible-Light-Induced Decarboxylative Cyclization/Hydrogenation Cascade Reaction to Access Phenanthridin-6-yl(aryl)methanol by an Electron Donor-Acceptor Complex
Shi, Wei,Ma, Fang,Li, Pinhua,Wang, Lei,Miao, Tao
, p. 13808 - 13817 (2020/11/20)
A novel and efficient visible-light-induced decarboxylative cyclization/hydrogenation cascade reaction of α-oxocarboxylic acids and 2-isocyanobiaryls has been developed. Without the need of any external photosensitizer, oxidant, and reductant, this method offers a mild and green approach for the synthesis of diverse alcohols in moderate to good yields. A mechanism indicated that an electron donor-acceptor complex-driven decarboxylation, radical addition/cyclization, and in situ photochemical reduction of ketones to alcohols could be involved in the reaction.
Reissert Compound Studies. XLV. The Phenanthridine Reissert Compound
Kant, Joydeep,Popp, Frank D.
, p. 425 - 427 (2007/10/02)
A series of phenanthridine Reissert compounds and Reissert analogs have been prepared using the trimethylsilyl cyanide method.The reactions of the conjugate base and fluoroborate salt have been studied and found, generally, to be similar to those of the i
