91879-71-9Relevant academic research and scientific papers
Radiation-Induced Alkylation of Quinoline Derivatives with Alcohol
Sugimori, Akira,Yamada, Tetsuo,Ishida, Hiroaki,Nose, Masayuki,Terashima, Keiko,Oohata, Noriko
, p. 3905 - 3910 (1986)
Gamma-irradiation of quinoline and its derivatives in alcohols brings about alkylation at the 2- or 4-position of pyridine ring.Hydroxyalkyl radicals play important roles in the radiation-induced alkylation with alcohol.The radiation-induced substitution of CF3CH2- and CF3CH(OH)- for H in pyridine and pyrimidine rings occurs in low yields.
A NEW GENERAL METHOD OF HOMOLYTIC ALKYLATION OF PROTONATED HETEROAROMATIC BASES
Castaldi, Graziano,Minisci, Francesko,Tortelli, Vito,Vismara, Elena
, p. 3897 - 3900 (2007/10/02)
Alkyl iodides and benzoyl peroxides provide a new general method of homolytic alkylation of protonated heteroaromatic bases.Yields are good and the substitution is selective in the positions ortho and para to the heteroatom.
