Bulletin of the Chemical Society of Japan p. 3905 - 3910 (1986)
Update date:2022-08-03
Topics:
Sugimori, Akira
Yamada, Tetsuo
Ishida, Hiroaki
Nose, Masayuki
Terashima, Keiko
Oohata, Noriko
Gamma-irradiation of quinoline and its derivatives in alcohols brings about alkylation at the 2- or 4-position of pyridine ring.Hydroxyalkyl radicals play important roles in the radiation-induced alkylation with alcohol.The radiation-induced substitution of CF3CH2- and CF3CH(OH)- for H in pyridine and pyrimidine rings occurs in low yields.
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