91936-00-4Relevant academic research and scientific papers
A NOVEL SYNTHESIS OF SILICON-CONTAINING AZIRIDINES
Lukevics, E.,Dirnens, V. V.,Goldberg, Y. S.,Liepinsh, E. E.,Kalvinsh, I. Ya.,Shimanska, M. V.
, p. C29 - C32 (1984)
Addition of methyl N,N-dichlorocarbamate to trimethylvinylsilane with subsequent reduction with sodium hydrosulphite afforded methyl N-(2-chloro-2-trimethylsilyl)ethylcarbamate.Intramolecular alkylation of the latter in a hexane/solid NaOH two-phase system in the presence of a phase transfer catalyst or under ultrasonic irradiation resulted in 1-carbomethoxy-2-trimethylsilylaziridine.Similarly, starting from trimethylallylsilane the 1-carbethoxy-2-(trimethylsilylmethyl)aziridine was prepared.
The synthesis of 2-trialkyIsilylaziridines from vinyltrialkylsilanes or the reaction of α-chloro-α-silyl carbanions with imines
Bassindale, Alan R.,Kyle, Patricia A.,Soobramanien, Marie-Claire,Taylor, Peter G.
, p. 1173 - 1180 (2007/10/03)
Three methods have been employed in the synthesis of 2-trialkylsilylaziridines. Firstly, reacting α-chloroa-silyl carbanions with imines. Secondly, from the corresponding vinylsilane, via addition of bromoazide to give the l-bromo-2-azide, followed by red
