91968-14-8Relevant academic research and scientific papers
Highly diastereo- and enantioselective copper-catalyzed domino reduction/aldol reaction of ketones with methyl acrylate
Deschamp, Julia,Chuzel, Olivier,Hannedouche, Jerome,Riant, Olivier
, p. 1292 - 1297 (2007/10/03)
(Chemical Equation Presented) A good choice: A new catalytic method was found for the construction of stereogenic quaternary carbon centers through a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ke
Catalytic enantioselective allylboration of ketones
Wada, Reiko,Oisaki, Kounosuke,Kanai, Motomu,Shibasaki, Masakatsu
, p. 8910 - 8911 (2007/10/03)
The first example of catalytic enantioselective allylboration and crotylboration of simple ketones is described. High enantioselectivity (up to 93% ee) was obtained using 3 mol % CuF-iPr-DuPHOS as a chiral catalyst and 4.5 mol % La(Oi/sup
