92007-41-5

Upstream product

• 92007-40-4 C₁₄H₂₄O₅S 
• 92542-77-3 (3'aα,5'α,6'aα)-hexahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalen]-5'-ol 
• 92007-39-1 (3'aα,5'β,6'aα)-hexahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalen]-5'-ol 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 112755-94-9 (3a'R,6a'S)-5,5-dimethyltetrahydro-1'H-spiro[1,3-dioxane-2,2'-pentalen]-5'(3'H)-one 
• 51716-63-3 cis-bicyclo[3. 3. 0]octane-3,7-dione 
• 100668-68-6 C₂₀H₂₈N₂O₄S 
• 208347-37-9 (3‘aR,6‘aS)-5,5-dimethylspiro[1,3-dioxane-2,5‘-2,3,3a,4,6,6a-hexahydro-1H-pentalenyl]-2’-ol 
• 481046-16-6 (3'aα,5'α,6'aα)-hexahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalen]-5'-yl-4-nitrobenzoate 

Downstream Products

• 92007-51-7 C₂₀H₂₆O₃Se 

Relevant academic research and scientific papers

An enantiodivergent trend in microbial Baeyer-Villiger oxidations of functionalized pentalenones by recombinant whole cells expressing monooxygenases from Acinetobacter and Pseudomonas

We have investigated the microbial Baeyer-Villiger oxidations of pentalenones by recombinant whole cells expressing cyclohexanone monooxygenase from Acinetobacter and cyclopentanone monooxygenase from Pseudomonas. The two enzymes display a distinguishable

Whole-cell mediated Baeyer-Villiger oxidation of functionalized bicyclo[3.3.0]ketones by recombinant E. coli

Recombinant whole cells of Escherichia coli overexpressing Acinetobacter sp. NCIMB 9871 cyclohexanone monooxygenase (E.C. 1.14.13.22) have been utilized for the Baeyer-Villiger oxidation of functionalized bicyclo[3.3.0]ketones. Prochiral substrates were d

THERMAL REARRANGEMENT OF DIVINYLCYCLOPROPANE SISTEMS. A NEW FORMAL TOTAL SYNTHESIS OF (+/-)-QUADRONE

The key step of a new approach to the total synthesis of the structurally and physiologically interesting sesquiterpenoid (+/-)-quadrone (1) involves thermal (Cope) rearrangement of the higly functionalized divynilcyclopropane derivative 8.The product 9 of this process is converted into 19, thus completing a formal total synthesis of (+/-)-1.

SYNTHESIS OF cis-BICYCLOOCT-3-ENE-2,7-DIONE, A HIGHLY FUNCTIONALIZED CYCLOPENTANOID INTERMIDIATE

cis-Bicyclooct-3-ene-2,7-dione (1) has been synthesized either from cis-bicyclooctane-3,7-dione (2) or the -cycloadduct 10 of 5-trimethylsilylcyclopentadiene with dichloroketene.As anticipated, the conjugated double bond of acetal 9 act