922-84-9Relevant academic research and scientific papers
HPLC studies on the photochemical formation of free radicals from malonic acid
Szalai, Istvan,Foersterling, Horst-Dieter,Noszticzius, Zoltan
, p. 3118 - 3120 (2007/10/03)
In the Belousov Zhabotinsky reaction, malonyl radicals formed during the oxidation of malonic acid by Ce4+ play an important role in the mechanism of the negative feedback loop. In the past, we have analyzed the end products in the Ce4+-malonic acid reaction applying HPLC technique. For comparison, we generated malonyl radicals by UV irradiation of solutions of malonic acid and we identified the reaction products. Two of these are the same as in the Ce4+-malonic acid reaction, but some additional products are also formed. To explain our experimental results, a new reaction path is proposed where malonyl radicals and hydrogen atoms are the first intermediates in the photochemical decomposition of the malonic acid. Mechanistic differences between this photochemical decomposition and the Ce4+-malonic acid reaction are also discussed.
HPLC studies on the organic subset of the oscillatory BZ reaction. 2. Two different types of malonyl radicals in the Ce4+-malonic acid reaction
Sirimungkala, Atchara,Foersterling, Horst-Dieter,Noszticzius, Zoltan
, p. 3051 - 3055 (2007/10/03)
Applying combined HPLC and NMR techniques, it was found that, besides the already known 1,1,2,2-ethanetetracarboxylic acid (ETA), monomalonyl malonate (MAMA) is also a product of the Ce4+-malonic acid reaction. This is indirect evidence that two different types of organic radicals are formed in the reaction: the alkyl and the carboxylato malonyl radicals. While ETA is a recombination product of two alkyl radicals, MAMA is formed in the recombination of one alkyl and one carboxylato radical.
