922733-67-3Relevant academic research and scientific papers
Synthesis, crystal structure and thermal decomposition of a novel praseodymium supermolecular complex
Chen,Ren,Gao
, p. 801 - 805 (2006)
A novel complex, [Pr(5-nip)(phen)(NO3)(DMF)] (5-nip: 5-nitroisophthalic acid; phen: 1,10-phenanthroline, DMF: N,N-dimethylformamide), was prepared and characterized by single crystal X-ray diffraction, elemental analysis, IR spectrum and DTG-DSC techniques. The results show that the crystal is monoclinic, space group P2(1)/n with a=11.0876(6) A, b=12.8739(7) A, c=16.9994(8) A; β=91.193(4)°, Z=4, D c=1.822 Mg m-3, F(000)=1320. Each Pr(III) ion is nine-coordinated by one chelating bidentate and two monodentate bridging carboxylate groups, one chelating bidentate nitryl group, one DMF molecule and one 1,10-phenanthroline molecule. The complex is constructed with one-dimensional ribbons featuring dinuclear units and the one-dimensional ribbons are further assembled into two-dimensional networks by strong π-π stacking interactions. The complex has high stability up to 500°C. The enthalpy change of formation of the compound in DMF was measured using an RD496-III type microcalorimeter with the value of -9.214±0.173 kJ mol-1.
Syntheses, characterization and the liquid-phase formation enthalpy changes of two new one-dimensional ribbon-like lanthanide supermolecular polymers
Ren, Yixia,Chen, Sanping,Gao, Shengli,Shi, Qizhen
, p. 649 - 653 (2008/10/09)
Two novel one-dimensional ribbon-like mixed-ligand supermolecular polymers, [Ln(5-nip)(phen)(NO3) (DMF)]n (Ln = Pr (1) and Ho (2)), assembled into two-dimensional networks by strong π-π stacking interactions, have been synthesized by
