92351-77-4Relevant academic research and scientific papers
Silver-catalyzed functionalization of esters by carbene transfer: The role of ylide zwitterionic intermediates
Gava, Riccardo,Fuentes, M. Angeles,Besora, Maria,Belderrain, Tomas R.,Jacob, Kane,Maseras, Feliu,Etienne, Michel,Caballero, Ana,Perez, Pedro J.
, p. 2206 - 2210 (2014/08/18)
The reaction of esters with ethyl diazoacetate catalyzed by the complex [F27-Tp4Bo,3CF2CF3Ag(acetone)] generates α-(acyloxy)acetates in moderate to high yields. This is a novel transformation in the context of carbene-transfer reactions from diazo compounds that, according to experimental and theoretical data, is suggested to occur through zwitterionic intermediates.
